Upgraded to 4.1 yesterday and been having loads of similar probs. In my case, restarting services (Policy Service indeed is a culprit), turning off/on the BB's wireless, and then resending the service book finally allows a user to complete an enterprise activation.
I'm still battling several other issues (such as my earlier post re. duplicate contacts and some oddities with individual BBs), but at least we've got most users finally working.
This upgrade was a total nightmare. I can't see how RIM will survive vs Windows Mobile in a few years...
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