Also - and this is serious and not an attempt to provoke or flame - you ought to stop using Outlook Express. Use regular Outlook if you have it, or download something better and free (Thunderbird works well) if you don't. Outlook Express is incredibly out-of-date and a big security nightmare.
As to your main question, I agree with the prior poster - just have your BB use the account. If the Internet E-mail Setup on the phone doesn't work, log into your T-Mobile account and use the Set Up Blackberry Internet E-mail (or similar) link - it gives you a little more control than the phone version.
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